Hisc hydrogen induced stress considerations 1 day course. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. Once hic initiates, hydrogen gas pressure drives crack. Oriani r a, josephic p h 1980 effect of hydrogen on the plastic properties of. Hic test, hydrogen induced cracking test, step wise cracking. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Hydrogen effect is greater near room temperature and decreases with increasing strain rate. Hydrogen induced cracking steel features, applications. Susceptibility to hydrogen induced stress cracking of. Metallurgical factors in stress corrosion cracking scc and hydrogeninduced cracking hic article in journal of solid state electrochemistry 7. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. The path of crack growth in hydrogen embrittled steels is a function of the stress intensity factor, k mpavm.
Experience has shown that stainless steels can suffer from hydrogen induced stress cracking hisc under cathodic protection in seawater. Hydrogen induced cracking hic in the oil and gas industry. The strain generated by the plastic deformation can cause residual stress and may decrease its hic resistance. Prior to 2003, hydrogen induced cracking hic testing was not incorporated into nace mr0175 iso 15156 and generally was not required for mildly sour environments i.
Hydrogen induced cracking of subsea duplex stainless steel twi. Sintef hydrogen induced stress cracking hisc sitemap norsk english. Hydrogen induced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. Hic testing is recommended to evaluate the resistance of pipeline and pressure vessel plate steels to hydrogen induced cracking corrosion caused by hydrogen absorption from aqueous sulfide corrosion. Hisc hydrogen induced stress cracking design and material considerations 1 day course if you would like further information on this course, please contact yeechin tang. At intermediate stage adsorbed hydrogen atoms hads are present. Environmental stress cracking esc is the premature cracking of a polymer due to the combined action of a stress and a fluid. Nonmetallic inclusions can affect resistance of steels to both general and localized corrosion, including pitting corrosion, stress corrosion cracking scc, and hydrogeninduced cracking hic. Hydrogen induced cracking and sulphide stress cracking of. Both hic and ssc occur due to embrittlement phenomenon related to the trapping of h atoms generated during the corrosion of steel by h 2 s.
Hydrogen cracking may also be called cold cracking or delayed cracking. In this project hydrogen charged samples of alloy 718 and alloy 725 have been exposed under tensile stress to establish critical stress levels for initiation of hisc. Hisc hydrogen induced stress cracking all acronyms. The differences between the flow stresses at point a before unloading and the yield strengths at point b after charging are the hydrogeninduced stresses. Hydrogen induced cracking hic assessment in a gas processing plant case study mohammed a abufour, mohammad. Hydrogen induced cracking hic and sulfide stress cracking ssc are well known as hydrogen related problems of linepipe steels exposed to a media containing hydrogen sulfide h 2 s. Hydrogeninduced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. It was not until much later, however, that hic started to be investigated and gained recognition as a potential problem in pipelines as a result of pipeline failures. Formation criterion of hydrogeninduced cracking in steel. Hydrogen induced cracking tests of high strength steels. Hydrogen blistering a special case of hydrogen damage is known as hydrogen blistering.
Processes or conditions involving wet hydrogen sulfide, i. May 19, 2009 hic is prevalent in wet h 2 s environments, which is often known as sour service and such cracking over a prolonged period of time without inspection, will reach a critical point and the steel component i. Sohic is a type of cracking that can easily lead to failure and needs to be mitigated. Cheng, effect of nonmetallic inclusions on hydrogeninduced cracking of api5l x100 steel, international journal of hydrogen energy 2010. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. Hydrogen enhanced localized plasticity help, hydrogen induced cracking hic and elastic. Investigation of oil and natural gas pipelines failure by hydrogen. Recent experience has demonstrated the risk of sscc and hic, sometimes known as hydrogen embrittlement he, of low strength steels subject to high residual stress derived from fabrication techniques. Stressorientated hydrogen induced cracking sohic susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogen induced cracking hic, sulphide stress cracking ssc and stress oriented hydrogen induced cracking sohic. Review of hydrogenassisted cracking models for application to.
Defects hydrogen cracks in steels identification twi. Safety, reliability and risks associated with water, oil and gas pipelines pp 115 129. Hydrogen induced cracking of low strength steels in. Hydrogen embrittlement and stress corrosion cracking. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. Hydrogen induced stress cracking hisc resistance and.
Steel quality susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. Relationship between hydrogeninduced cracking and type i. The control valve body failed due to combination of ssc and hic cracking in wet h2s environment. Metallurgical factors in stress corrosion cracking scc. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hydrogen induced cracking steel features, applications and. Initiation of stress corrosion cracking and hydrogeninduced. Introduction hydrogeninduced cracking sulfide stress cracking references. To our surprise, it was not true in the studied case. It is made up of a series of hic hydrogen induced cracking cracks that are stacked perpendicularly in the direction of through wall cracks and driven by high residual or applied stresses.
Both steels showed generalized corrosion in solution 177a, and a. Hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. Hydrogeninduced cracking susceptibility in highstrength weld metal a formula is proposed to estimate minimum preheat and interpass temperatures which help prevent hydrogeninduced cracking n. Hydrogen delayed cracking of highstrength weldable steels 7 these reactions take place in two steps. That means the hydroxyle ions decharge separately one by one. Because stress corrosion cracks frequently initiate at pits, and pits nucleate at sulfides, the presence of sulfides is likely to affect the scc process. Safety, reliability and risks associated with water, oil and gas pipelines pp 115129. Unstressed test specimens are exposed to a solution at temperature of. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Hydrogen embrittlement occurs in a number of forms but the common features are an applied tensile stress and hydrogen dissolved in the metal. Induced cracking and sulfide stress cracking request. Hydrogen induced crack resistant hic steel plate brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock. Hydrogeninduced cracking hic and sulfide stress cracking ssc are well known as hydrogenrelated problems of linepipe steels exposed to a media containing hydrogen sulfide h 2 s.
Mar 25, 2009 nonmetallic inclusions can affect resistance of steels to both general and localized corrosion, including pitting corrosion, stress corrosion cracking scc, and hydrogen induced cracking hic. Corrosionpedia what is hydrogeninduced cracking hic. Simply put, hydrogen induced cracking damage increases as the level of hydrogen sulphide increases. Nace international has adopted the term hydrogeninduced cracking hic. The effect of hydrogen induced cracking on the integrity of steel. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Both hic and ssc occur due to embrittlement phenomenon related to the trapping of h atoms generated during the corrosion of steel by h 2 s 1, 2. Hydrogen induced cracking hic resistance in hsla api 5l. Aermet100 steel, the threshold stress intensity for critical hic kth can be.
Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. A new criterion for hydrogeninduced cracking hic that includes. The stressstrain curves of the specimens loaded in air before and after charging with various current densities i are shown in fig. The steps of a possible mechanism of hydrogeninduced cracking hic can be, first. According to hic and ssc laboratory tests the best. Cracks can develop by both transgranular and intergranular paths. Brown a, jones c l 1984 hydrogen induced cracking in pipeline steels. Nanis l 1965 hydrogen permeation in metals as a function of stress temperature and. Hydrogeninduced cracking susceptibility in highstrength. Vargas pm, wastberg s and woollin p, stress based design guidelines for hydrogen induced stress cracking hisc avoidance in duplex materials, proc conf omae 200979504.
It is often assumed that hic is just a subcategory of sulfide stress cracking. Sulfide stress corrosion cracking and hydrogen induced cracking of. This paper presents results from a test program examining the hisc susceptibility of 25% cr super duplex stainless steel uns s32750 at temperatures up to 150 0 c. Study of correlation between hydrogeninduced stress and. It is associated with the phenomenon of crazing and solvent plasticization of the polymer.
It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms.
Hic test, hydrogen induced cracking test, step wise. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. A comparative study of hydrogeninduced cracking resistances of. It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. The list of acronyms and abbreviations related to hisc hydrogen induced stress cracking. Hydrogen induced cracking safe materials operating limits. Particularly common to the oil and gas industry where the use of steel. According to iso 15156, hydrogen induced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. Another type of hydrogen corrosion, stressorientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the. Hydrogen induced cracking and sulphide stress cracking of carbonmanganese steels 517 introduction, sulphide inclusions are considered as the most dangerous sites for hic initiation. Sulfide stress cracking ssc vs hydrogen induced cracking.
The boltloaded specimen was subjected to both acid and electrochemical cell environments in order to produce hydrogen. Efc publication 17, 2nd edition, corrosion resistant alloys for oil and gas production. Unstressed test specimens are exposed to a solution at temperature of 25deg cent with continuous h2s gas flow. Cortest offers hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on metal samples in hydrogen enriched aqueous environments such as those in h 2 ssour service applications hic tanks are suitable for samples specified in nace tm0284 as well as 3 and 4 point bend fixtures specified in both nace tm0177 and astm g39. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Hydrogen induced cracking test tank test methods nace tm0284 astm g39 material of construction polypropylene, pvc, or glass capacities up to 55 liters cortest offers a variety of different hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on a metal sample in a hydrogen enriched. Request pdf metallurgical factors in stress corrosion cracking scc and hydrogeninduced cracking hic nonmetallic inclusions can affect resistance of. Environmental stress cracking of polypropylene springerlink. Hydrogen combines with carbon within the alloy and forms methane.
Specificationsgrades asmeastm saa 516 grades 606570. Cortest offers hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on metal samples in hydrogen enriched aqueous environments such as those in h 2 ssour service applications. Pdf hydrogen induced cracking safe materials operating. Examples of hydrogen embrittlement are cracking of weldments or hardened steels when exposed to conditions which inject hydrogen into the component. In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogeninduced cracking hic, sulphide stress cracking ssc and stressoriented hydrogeninduced cracking sohic. According to iso 15156, hydrogeninduced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. These samples were placed on a plastic grid at 25 mm from the bottom of the vessel. May 22, 2018 hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Hydrogen induced cracking tests were conducted on high strength steels and nickeliron base alloys using the constant displacement boltloaded compact specimen. A test project to examine the susceptibility of hydrogen induced stress cracking hisc has been executed. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry. Hydrogen induced cracking hic from advanced ndt solutions. In this issue, the characteristic features and principal causes of hydrogen cracks are described. Another type of hydrogen corrosion, stress orientated hydrogen induced cracking. Hydrogen blistering has been recognized since the 1940s as a problem in vessel handling sour products. Metallurgical factors in stress corrosion cracking scc and. In this article the chemical and metallurgical genesis of hic, its harmful impact on.
The hydrogeninduced cracking hic susceptibility of weld met. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Large manganese sulphides were found in metallographic specimens not initiating any cracks.
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